Fluoride anions: Unexploited but effective halogen bond acceptors
نویسندگان
چکیده
Due to their high electron density, fluoride anions can be considered the most effective halogen bond (HaB) acceptors among halides. However, under common experimental conditions, Fˉ is hardly available as dry species. Herein we report that specific crystallization conditions a hydrogen bond-free functioning donor of density obtained, with formed HaBs constituting driving force observed crystal packings. Computations confirm strength these compared analogous interactions involving other
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ژورنال
عنوان ژورنال: Chemistry-an Asian Journal
سال: 2023
ISSN: ['1861-471X', '1861-4728']
DOI: https://doi.org/10.1002/asia.202300520